TNPSC Executive Officer Grade-I Chemical Engineering - 2012

  • Question 2 :
  • In a closed system, there is 

  • No exchange of energy of the system
  • Exchange of mass with the surroundings
  • Exchange of mass and energy with the surroundings
  • Exchange of energy with the surroundings and not the mass.
  • Question 16 :
  • Charles law for a given mass of an ideal gas is

  • ratio of the volume to temperature is constant
  • ratio of the temperature to volume is constant
  • ratio of the pressure to volume is constant
  • product of pressure and volume is constant
  • Question 17 :
  • Molality is defined as

  • The number of moles of solute dissolved in 1 litre of solution
  • The number of gram equivalent dissolved in 1 litre of solution
  • The number of mole of solute dissolved in 1 kilogram of solvent
  • The number of gram of solute dissolved in 1 kg of solvent.
  • Explanation:

     

     

  • Question 18 :
  • For an ideal gas mixture

  • volume % = weight % = pressure %
  • volume % = mole % = pressure %
  • mole % = molecular weight % = pressure %
  • none of these
  • Question 21 :
  • All oxidation reactions are

  • Endothermic with irreversible
  • Endothermic with reversible
  • Exothermic with reversible
  • Exothermic with irreversible.
  • Question 29 :
  • Crushing efficiency is the ratio of

  • surface energy created by the crushing to the energy absorbed by the solid
  • the energy absorbed by the solid to that fed to the machine
  • the energy fed to the machine to the surface energy created by the crushing
  • the energy absorbed by the solid to the surface energy created by the crushing.
  • Question 30 :
  • Rittinger's crushing law states that 

  • work required to form a particle of any size is proportional to the square of the surface to volume ratio of the product.
  • work required to form a particle of a particular size is proportional to the square root of the surface to volume ratio of the product.
  • work required in crushing is proportional to the new surface created
  • for a given machine and feed, crushing efficiency is dependent on the size of feed and product.
  • Question 31 :
  • Work index is defined as the

  • gross energy [kWh/ton of feed] needed to reduce very large feed to such a size that 80% of the product passes a 100 micron screen.
  • energy needed to crush one ton of feed to 200 microns
  • energy [kWh/ton of feed] needed to crush small feed to such a size that 80% of the product passes a 200 mesh screen.
  • energy needed to crush one ton of feed to 100 microns.
  • Explanation:

     

     

  • Question 36 :
  • A classifier is a device that

  • Separates solids into two fractions
  • Virtually removes all the particles from a liquid
  • Settles the particles from a liquid by sedimentation
  • Helps to suspend the particle in the liquid
  • Question 41 :
  • Contact process

  • yields acid of higher concentration than chamber process
  • yields acid of lower concentration than chamber process
  • is obsolete
  • eliminates absorber.
  • Question 44 :
  • Gypsum is 

  • calcium chloride
  • potassium sulphate
  • sodium sulphate
  • calcium sulphate
  • Question 45 :
  • Oil is 

  • a mixture of glycerides
  • a mixture of glycerides of fatty acids
  • solid at normal temperature
  • ester of alcohols other than glycerin.
  • Question 46 :
  • Unsaturated oils compared to saturated oils have

  • lower melting point and higher reactivity to oxygen
  • higher melting point and higher reactivity to oxygen
  • lower melting point and lower reactivity to oxygen
  • higher melting point and lower reactivity to oxygen
  • Question 58 :
  • Fire clay is

  • a basic refractory
  • an acidic refractory
  • a neutral refractory
  • not a refractory material
  • Question 60 :
  • A Newtonian fluid is one which

  • is frictionless and imcompressible
  • has a linear relationship between the magnitude of applied shear stress and the resulting rate of deformation.
  • has a non-linear relationship between the magnitude of applied shear stress and the resulting rate of deformation
  • has a vapour pressure of 1 N/m2 at 250 C
  • Question 65 :
  • Cavitation in fluid flow occurs when

  • the pressure of flow reaches to a value close to its vapour pressure
  • the total energy increase suddenly
  • the total energy decreases suddenly
  • the fluid velocity decreases to zero.
  • Question 75 :
  • In a finned tube heat exchanger

  • only heat transfer area is augmented
  • only film coefficient is augmented
  • both heat transfer area & film coefficient are augmented
  • none of these
  • Question 76 :
  • 25 per cent cut segmental baffle means

  • a baffle plate whose height is 25% of the inside diameter of the shell
  • a baffle plate whose height is 75% of the inside diameter of the shell
  • a baffle plate whose height is 25% of the inside diameter of the tube
  • a baffle plate whose height is 25% of the length of tube.
  • Question 77 :
  • Capacity of an evaporator is defined as

  • the number of kilograms of solvent vapourized per hour
  • the number of kilograms of solvent vapourized per kilogram of steam fed to the evaporator
  • the number of kilograms of steam consumed per hour
  • the number of kilograms of steam consumed per kilogram of sovent vapourized
  • Question 78 :
  • Economy of an evaporator is defined as

  • the number of kilograms of steam consumed per hour
  • the number of kilograms of steam consumed per kilogram of solvent vaporized
  • the number of kilograms of solvent vaporized per hour
  • the number of kilograms of solvent vaporized per kilogram of steam fed to the evaporator
  • Question 86 :
  • A batch reactor is characterized by

  • Constant residence tim
  • Variation in extent of reaction and proportion of the reaction mixture with time
  • Variation in reactor volume
  • Very low conversion
  • Question 90 :
  • Space velocity of 5 hr-1 means that

  • Five reactor volume of feed (at specified conditions) are being fed into the reactor per hour
  • After every 5 hours, the reactor is being filled with the feed
  • Cent per cent conversion can be achieved in at least 5 hours
  • A fixed conversion of a given batch of feed takes 5 hours
  • Question 91 :
  • For a recycle reactor the recycle ratio is given by

  • R= Volume of fluid returned to the reactor inlet/Volume of fluid leaving the system
  • R = Volume of fluid leaving the system/Volume of fluid returned to the reactor outlet
  • R= Volume of fluid leaving the system/Volume of fluid retained in the reactor
  • R= Volume of fluid retained in the reactor/Volume of fluid leaving the system
  • Question 93 :
  • In an ideal P.F.R at steady state conditions 

  • the composition of reactants remains constant along a flow path
  • the conversion of the reactant varies from point to point along a flow path
  • there is no lateral mixing of fluid
  • all of these.
  • Question 96 :
  • For a batch system, the selectivity (S) is

  • S = Moles of desired product formed/Moles of undesired product formed
  • S= Moles of desired product formed/Moles of feed admitted to the system
  • S= Moles of undesired product formed/Moles of desired product formed
  • S = Moles of desired product formed/ Volume of fluid leaving the system
  • Question 98 :
  • Inversion of cane sugar is a 

  • Bimolecular reaction with second order
  • Bimolecular reaction with first order
  • Unimolecular reaction with second order
  • Pseudo-unimolecular reaction with first order.
  • Question 99 :
  • A photochemical reaction is

  • Catalyzed by light
  • Accompanied with emission of light
  • Initiated by light
  • Used to convert heat energy to light
  • Question 111 :
  • The general condition for stability of a continuous system is 

  • the roots of the characteristic equation fall in the right half of the complex plane.
  • the roots of the characteristic equation fall in the left half of the complex plane
  • the roots of the characteristic equation fall in the centre of the complex plane
  • Question 141 :
  • Relative humidity is the ratio of

  • partial pressure of the vapour to the vapour pressure of the liquid at room temperature
  • partial pressure of the vapour to the vapour pressure of the liquid at gas temperature
  • actual humidity to saturation humidity
  • none of these
  • Question 143 :
  • At plait point of a ternary system

  • the selectivity of solvent will be unity
  • the distribution coefficient for solute will be unity
  • the density difference between the two equilibrium phases becomes zero
  • all of these
  • Question 149 :
  • Constant rate period is that drying period during which 

  • the rate of vaporization per units of drying surface area is constant
  • the rate of vaporization continually decreases with time.
  • the rate of vaporization continually increases with time
  • the moisture content of the substance remains constant
  • Question 185 :
  • Pick out the wrong statement :

  • Net worth means paid up share capital and reserve & surplus (i.e. share-holder's equity)
  • Return on equity = profit after tax/net worth
  • Working capital turnover ratio = sales / net working capital
  • Total cost of production is more than net sales realization (NSR) at break-even point.
  • Question 193 :
  • Pick out the wrong statement :

  • Gross margin = Net income - Net expenditure
  • Net sales realization (NSR) = Gross sales - Selling expenses
  • At break-even point, NSR is more than the total production cost
  • Net profit = Gross margin - Depreciation - Interest
TNPSC Executive Officer Grade-I Chemical Engineering - 2012
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