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Home Solved Question Papers TNPSC TNPSC Executive Officer Grade-I Chemical Engineering - 2012
199 Questions
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TNPSC Executive Officer Grade-I Chemical Engineering - 2012

  • Question 2 :
  • In a closed system, there is 

  • ANo exchange of energy of the system
  • BExchange of mass with the surroundings
  • CExchange of mass and energy with the surroundings
  • DExchange of energy with the surroundings and not the mass.
  • Question 8 :
  • The change in entropy (∂S) for reversible process is

  • A(∂S) = Change of heat transfer / absolute temperature
  • B(∂S) = Absolute temperature / change of heat transfer
  • C(∂S) = Change of heat transfer / change of mass transfer
  • Dnone of these
  • Explanation:

     

     

  • Question 16 :
  • Charles law for a given mass of an ideal gas is

  • Aratio of the volume to temperature is constant
  • Bratio of the temperature to volume is constant
  • Cratio of the pressure to volume is constant
  • Dproduct of pressure and volume is constant
  • Question 17 :
  • Molality is defined as

  • AThe number of moles of solute dissolved in 1 litre of solution
  • BThe number of gram equivalent dissolved in 1 litre of solution
  • CThe number of mole of solute dissolved in 1 kilogram of solvent
  • DThe number of gram of solute dissolved in 1 kg of solvent.
  • Explanation:

     

     

  • Question 18 :
  • For an ideal gas mixture

  • Avolume % = weight % = pressure %
  • Bvolume % = mole % = pressure %
  • Cmole % = molecular weight % = pressure %
  • Dnone of these
  • Question 21 :
  • All oxidation reactions are

  • AEndothermic with irreversible
  • BEndothermic with reversible
  • CExothermic with reversible
  • DExothermic with irreversible.
  • Question 29 :
  • Crushing efficiency is the ratio of

  • Asurface energy created by the crushing to the energy absorbed by the solid
  • Bthe energy absorbed by the solid to that fed to the machine
  • Cthe energy fed to the machine to the surface energy created by the crushing
  • Dthe energy absorbed by the solid to the surface energy created by the crushing.
  • Question 30 :
  • Rittinger's crushing law states that 

  • Awork required to form a particle of any size is proportional to the square of the surface to volume ratio of the product.
  • Bwork required to form a particle of a particular size is proportional to the square root of the surface to volume ratio of the product.
  • Cwork required in crushing is proportional to the new surface created
  • Dfor a given machine and feed, crushing efficiency is dependent on the size of feed and product.
  • Question 31 :
  • Work index is defined as the

  • Agross energy [kWh/ton of feed] needed to reduce very large feed to such a size that 80% of the product passes a 100 micron screen.
  • Benergy needed to crush one ton of feed to 200 microns
  • Cenergy [kWh/ton of feed] needed to crush small feed to such a size that 80% of the product passes a 200 mesh screen.
  • Denergy needed to crush one ton of feed to 100 microns.
  • Explanation:

     

     

  • Question 36 :
  • A classifier is a device that

  • ASeparates solids into two fractions
  • BVirtually removes all the particles from a liquid
  • CSettles the particles from a liquid by sedimentation
  • DHelps to suspend the particle in the liquid
  • Question 41 :
  • Contact process

  • Ayields acid of higher concentration than chamber process
  • Byields acid of lower concentration than chamber process
  • Cis obsolete
  • Deliminates absorber.
  • Question 44 :
  • Gypsum is 

  • Acalcium chloride
  • Bpotassium sulphate
  • Csodium sulphate
  • Dcalcium sulphate
  • Question 45 :
  • Oil is 

  • Aa mixture of glycerides
  • Ba mixture of glycerides of fatty acids
  • Csolid at normal temperature
  • Dester of alcohols other than glycerin.
  • Question 46 :
  • Unsaturated oils compared to saturated oils have

  • Alower melting point and higher reactivity to oxygen
  • Bhigher melting point and higher reactivity to oxygen
  • Clower melting point and lower reactivity to oxygen
  • Dhigher melting point and lower reactivity to oxygen
  • Question 58 :
  • Fire clay is

  • Aa basic refractory
  • Ban acidic refractory
  • Ca neutral refractory
  • Dnot a refractory material
  • Question 60 :
  • A Newtonian fluid is one which

  • Ais frictionless and imcompressible
  • Bhas a linear relationship between the magnitude of applied shear stress and the resulting rate of deformation.
  • Chas a non-linear relationship between the magnitude of applied shear stress and the resulting rate of deformation
  • Dhas a vapour pressure of 1 N/m2 at 250 C
  • Question 65 :
  • Cavitation in fluid flow occurs when

  • Athe pressure of flow reaches to a value close to its vapour pressure
  • Bthe total energy increase suddenly
  • Cthe total energy decreases suddenly
  • Dthe fluid velocity decreases to zero.
  • Question 75 :
  • In a finned tube heat exchanger

  • Aonly heat transfer area is augmented
  • Bonly film coefficient is augmented
  • Cboth heat transfer area & film coefficient are augmented
  • Dnone of these
  • Question 76 :
  • 25 per cent cut segmental baffle means

  • Aa baffle plate whose height is 25% of the inside diameter of the shell
  • Ba baffle plate whose height is 75% of the inside diameter of the shell
  • Ca baffle plate whose height is 25% of the inside diameter of the tube
  • Da baffle plate whose height is 25% of the length of tube.
  • Question 77 :
  • Capacity of an evaporator is defined as

  • Athe number of kilograms of solvent vapourized per hour
  • Bthe number of kilograms of solvent vapourized per kilogram of steam fed to the evaporator
  • Cthe number of kilograms of steam consumed per hour
  • Dthe number of kilograms of steam consumed per kilogram of sovent vapourized
  • Question 78 :
  • Economy of an evaporator is defined as

  • Athe number of kilograms of steam consumed per hour
  • Bthe number of kilograms of steam consumed per kilogram of solvent vaporized
  • Cthe number of kilograms of solvent vaporized per hour
  • Dthe number of kilograms of solvent vaporized per kilogram of steam fed to the evaporator
  • Question 86 :
  • A batch reactor is characterized by

  • AConstant residence tim
  • BVariation in extent of reaction and proportion of the reaction mixture with time
  • CVariation in reactor volume
  • DVery low conversion
  • Question 90 :
  • Space velocity of 5 hr-1 means that

  • AFive reactor volume of feed (at specified conditions) are being fed into the reactor per hour
  • BAfter every 5 hours, the reactor is being filled with the feed
  • CCent per cent conversion can be achieved in at least 5 hours
  • DA fixed conversion of a given batch of feed takes 5 hours
  • Question 91 :
  • For a recycle reactor the recycle ratio is given by

  • AR= Volume of fluid returned to the reactor inlet/Volume of fluid leaving the system
  • BR = Volume of fluid leaving the system/Volume of fluid returned to the reactor outlet
  • CR= Volume of fluid leaving the system/Volume of fluid retained in the reactor
  • DR= Volume of fluid retained in the reactor/Volume of fluid leaving the system
  • Question 93 :
  • In an ideal P.F.R at steady state conditions 

  • Athe composition of reactants remains constant along a flow path
  • Bthe conversion of the reactant varies from point to point along a flow path
  • Cthere is no lateral mixing of fluid
  • Dall of these.
  • Question 96 :
  • For a batch system, the selectivity (S) is

  • AS = Moles of desired product formed/Moles of undesired product formed
  • BS= Moles of desired product formed/Moles of feed admitted to the system
  • CS= Moles of undesired product formed/Moles of desired product formed
  • DS = Moles of desired product formed/ Volume of fluid leaving the system
  • Question 98 :
  • Inversion of cane sugar is a 

  • ABimolecular reaction with second order
  • BBimolecular reaction with first order
  • CUnimolecular reaction with second order
  • DPseudo-unimolecular reaction with first order.
  • Question 99 :
  • A photochemical reaction is

  • ACatalyzed by light
  • BAccompanied with emission of light
  • CInitiated by light
  • DUsed to convert heat energy to light
  • Question 111 :
  • The general condition for stability of a continuous system is 

  • Athe roots of the characteristic equation fall in the right half of the complex plane.
  • Bthe roots of the characteristic equation fall in the left half of the complex plane
  • Cthe roots of the characteristic equation fall in the centre of the complex plane
  • Question 141 :
  • Relative humidity is the ratio of

  • Apartial pressure of the vapour to the vapour pressure of the liquid at room temperature
  • Bpartial pressure of the vapour to the vapour pressure of the liquid at gas temperature
  • Cactual humidity to saturation humidity
  • Dnone of these
  • Question 143 :
  • At plait point of a ternary system

  • Athe selectivity of solvent will be unity
  • Bthe distribution coefficient for solute will be unity
  • Cthe density difference between the two equilibrium phases becomes zero
  • Dall of these
  • Question 149 :
  • Constant rate period is that drying period during which 

  • Athe rate of vaporization per units of drying surface area is constant
  • Bthe rate of vaporization continually decreases with time.
  • Cthe rate of vaporization continually increases with time
  • Dthe moisture content of the substance remains constant
  • Question 185 :
  • Pick out the wrong statement :

  • ANet worth means paid up share capital and reserve & surplus (i.e. share-holder's equity)
  • BReturn on equity = profit after tax/net worth
  • CWorking capital turnover ratio = sales / net working capital
  • DTotal cost of production is more than net sales realization (NSR) at break-even point.
  • Question 193 :
  • Pick out the wrong statement :

  • AGross margin = Net income - Net expenditure
  • BNet sales realization (NSR) = Gross sales - Selling expenses
  • CAt break-even point, NSR is more than the total production cost
  • DNet profit = Gross margin - Depreciation - Interest